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PostWysłany: Nie 5:48, 20 Lut 2011    Temat postu: mbt shoes on sale Infrared Spectroscopy of aniline

Infrared Spectroscopy of aniline and copolymerization of propylene oxide and copolymer characterization of the mechanism


(Infrared spectroscopy in organic chemistry and pharmaceutical chemistry) [M], Bering: SciencePress, 2002,333:335 LiG. C. , ZhangZ. K. . Macromolecules [J] ,2004,37:2683 - 2685BenyoucefA. . Hue ~ aF. , VazquezJ. L. , Eta1. . Europ. Polym. J. [J], 2005,41:843 _852HasikM. ,mbt shoes on sale, DrelinkiewiczA. , WendaE. , Eta1. . J. Mo1. Struc. IJI,discount cosmetics mac, 2o0l ,596:89 - 99StudiesontheMechanismofCopolymerizationofAnilineandPropyleneOxideandCharacterizationofCopolymerv / aFTIRTechniqueLIMei-Chao,. , HUJia-Qi. , LIUYan-Na. , MAChun-An. (1.ResearchCenterD plant AnalysisandMeasurement, 2.CollegeChemicalEngineeringandMaterialScience, StateKeyLaboratoryBreedingBaseGreenChemistry-SynthesisTechnology,tory burch outlet, ZhejiangUniversityD Plant Technology, Hangzhou310032, China) AbstractCopolymerizationisoftenusedasoneofthemostimportantmethodtoimprovethephysicalandchemicalpropertiesofapolymer. Propyleneoxideisoftenaddedtotheelectrolyteduringelectrochemicalpoly-merizationtoimprovesomepropertiesofthepolymer. Therefore, polyaniline-poly (propyleneoxide) (PAN-PPO) wassynthesizedinaqueoussolutioncontaininganilineandpropyleneoxidebyelectrochemicalmethodinthispaper. / NsituF1] Rspectroscopywasusedtoinvestigateitselectrochemicalcopolymerizationmechanism. Itshowedthat a ring-openingreactionofpropyleneoxidemightbeinitiatedbyradicalcatalystfromanilineanditsoligomer, andthencopolymerizationofanilineandpropyleneoxidetookplacetoformstructureswithali-phatic-aromaticether. Inaddition, thePAN-PPOfilmformationwasregularfromthemiddletotwosidesontheplatinumsurface, whichwascharacterizedbyFTIRmicroscopicimagetechnique. KeywordsAniline; Propyleneoxide; InsituFTIR; FTIRmicroscopicimage (Ed.: S,tory burch shoes, I)
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