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ORANGE EKSTRAKLASA
Dołączył: 03 Mar 2011
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 Wysłany: Sob 9:17, 02 Kwi 2011 |
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C60O3 isomers and spectra
, HANCC. ElectrosprayandlaserdesorptionionizationstudiesofC60OandisomersofC60O2 [J]. JPhysChem ,1995,99:14907-14910. [7] BALCHAL, COSTADA, NOLLBC, ela1.0xidationofbuckminsterfullerenewithm-ch1oroperoxybenzoicacid. CharacterizationofaCsisomerofthediepoxideC60Oz [J]. JAmerChemSoc ,1995,117:8926-8932. [8] HAMANoT, MASHINOT, HIROBEM. Oxidationof [6O] fullerenebycytochromeP. 50chemicalmodels [J]. JChemSoc, ChemCommun ,1995,15:1537-1538. [9] BALCHAL, COSTADA, LEEJW,[link widoczny dla zalogowanych], ela1. Directingeffectsinafullereneepoxideaddition: Formationandstructura1characterizationof (C60O) Ir (CO) CI (P (C6H5) 3) z [J]. InorgChem ,1994,33:2071-2072. [1O] H1RSCHA, SOlA, KARFuNKELHR. TitrationofC60: Amethodforthesynthesisoforganofullerenes [J]. AngewChem: IntEdEng ,1992,31:766-768. [11] BINIR, PR0CACCIP, SALVIPR, ela1. Thefar-infraredspectrumofcrystallinefullereneC60 [J]. JPhysChem, 1993,97:10580.10584. StructureandspectraofC6003isomersMIWei-hong, LIUYi-jing, HAOCe (Dept.ofChem., DalianUniv.ofTechno1., Dalian116024.China) Abstract: ThereactionofC6owithozoneinbenzeneresultsintheformationofC60oxidesatroomtemperature. ThemixtureoftheproductswasisolatedbyHPLC. TwoisomersofC6oO3wereisolatedandtheUV-Visspectraofbothisomerswereobtained. Onthebasisoftheexperimentaldata, theequilibriumstructures, enthalpyofformation, dipolemoment, electronicandIRspectraofthepossibleisomerswerecalculatedbyAM1andINDOsemi-empiricalquantumchemicalmethods. Thepossiblestructuresofbothisomersareproposed. Thetheoreticalcomputationresultsareconsistentwiththeexperimentalones. Keywords: C6o03isomers; HPLC; UV-Visspectra; AM1; INDO
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